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Additional resources for High temperature surface engineering : proceedings of the Sixth International Conference in the series "Engineering the surface", 23-25 September 1997, Edinburgh Conference Centre, Edinburgh, UK
Sample text
JIMENEZ,*t D. J. BAXTER,* J. F. NORTON* and F. J. PEREZt *EC, IRC, Institute for Advanced Materials, 1755 ZG Petten, NL tUniversidad Complutense de Madrid, Avda. Complutense SIN, 28040 Madrid, SP ABSTRACT The microstructures of vacuum plasma sprayed (VPS) AlISi and air plasma sprayed (APS) Ni/CrlSi coatings on a model Fe-12%Cr alloy and on the commercial alloys HeM 12 and Sanicro 28, and their corrosion behaviour in a simulated non-equilibrium coal gasifier heat exchanger atmosphere (H2-64CO-3.
2% independent on scale thickness implies a first indication of a brittle scale behaviour. The latter was confirmed by microstructural studies which revealed brittle intergranular rupture. Such a material response allows the description of the scale properties in terms of fracture toughness. 15 Typical cracking features of the Al203-scale on deformed MA 956 after long term exposure, 5200hlll00°C; (a) multiple cracking and formation of new Al203 at the scale-alloy interface and (b) crack passing around a macropore.
5 urn. For thicker scales variations in the grain shape appeared for the region beneath the layer of columnar grains. 5 urn were observed. As illustrated in Fig. e. increasing scale thickness. According to the analysis given in Fig. 3, the compositional defects MECHANICAL INTEGRITY OF ALUMINA SCALES ON MA 956 45 30~------------------------~ E • deformed samples o non-deformed samples 10 :1. (IJ~ (IJ Q) ~co ;5 Q) a3 o (f) 1+-~~~~~~~~~~~~~ 10 100 1000 6000 Time, h Fig. 1 Scale thickness versus time for MA 956 at 1100°C.